FMC CORP CHEMICAL PRODUCTS GROUP

PHILADELPHIA, PA 19103-3230 US

Telephone: 215-200-6000

Cage: 93090

PHOSPHOROUS OXYCHLORIDE (SARA III)

CAS: 10025-87-3

RTECS: TH4897000

Fraction By Weight: 99%

OSHA PEL 0.1 PPM

ACGIH TLV: 0.1 PPM; 9192

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

LD50 LC50 Mixture:LD50 RAT ORAL 380 MG/KG.(SEE SUPP DA)
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EYES:LIQ & VAP EXTREMELY CORR.DIRECT
CONTACT MAY CAUSE IRREVERSIBLE TISSUE DESTRUCTION INCLUDING
BLINDNESS.SKIN:LIQ & VAP EXTREMELY CORR.DERMATITIS.INGEST:CORR OF
MOUTH,THROAT & STOMACH.INHAL:CHRONIC EFFECTS INCLUDE ASTHMATIC
BREATHING.ABSORPTION MAY LEAD TO LIVER DAMAGE.ALBUMINUREA.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:EYES:CORR & SEV IRRIT ON DIRECT CONTACT.VAP
IRRIT.SKIN:CORR & DERM.INGEST:CORR OF MOUTH,THROAT &
STOMACH.INHAL:EXPOS TO VAP:POSS PULM IRRIT & INFLAM,COUGH,PULM
EDEMA (MAY BE DELAYED 2-6 HRS FOR SHORT INHAL EXPOS OR 12-24 HRS
IN MOD TO SEV EXPOS).CHRONIC:PULM IRRIT,COUGH,ASTHMATIC
BRTHG.RARELY CARDIAC DISTURB,(SEE SUPP)
Medical Cond Aggravated by Exposure:N/K

First Aid:EYES:IMMED IRRIGATE W/ LRG AMT H*2O FOR AT LEAST 15
MIN,LIFTING LIDS OCCASIONALLY.SEE OPHTHALMOLOGIST.SKIN:WASH
THOROUGHLY W/ LRG AMT H*2O.CALL MD.INGEST:DRINK LRG AMT H*2O TO
DILUTE.CALL MD.INHAL:REM OVE FROM EXPOSURE AND ADMINISTER
OXYGEN.SEE MD.

Flash Point:NONE
Lower Limits:NONFLAMMABLE
Upper Limits:NONFLAMMABLE
Extinguishing Media:CO*2,DRY CHEMICAL,SAND.DANGER:DO NOT USE WATER.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT .DANGER:DO NOT USE WATER
Unusual Fire/Explosion Hazard:VIOLENT RXN W/ H*2O,PRDCS HEAT & TOX CORR
FUMES (HCL & PHOSPHORIC ACID).POSS FLASH FIRE ON CONTACT W/
H*2O.HAZ DECOMP PROD:PHOSPHORUS ACIDS & HCL.

Spill Release Procedures:DIKE TO CONTAIN FLOW.KEEP MATL OUT OF STREAMS
& SEWERS.ABSORB SPILLED MATL ON COMMERCIAL OIL ABSORBANT SAND OR
DIRT.PUT THE CONTAMINATED ABSORBANT INTO A DOT APPROVED CONTAINER &
DISPOSE OF ACCORDING TO THE METHODS OUTLINED IN WASTE DISPOSAL
METHOD.
Neutralizing Agent:N/K

Handling and Storage Precautions:DO NOT STORE IN VIC OF OXIDIZERS OR
ORGANIC MATLS.PROTECT CONTRS FROM PHYSICAL DMG.HANDLE IN EFTIVE
DRAFT OR OUTDOORS SURROUNDED BY OPEN AIR SHIELDS.
Other Precautions:LABEL:CORROSIVE & POISON.

Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR
EXPOSURE OF CONCERN .
Ventilation:LOCAL AND GENERAL VENTILATION NECESSARY TO KEEP AIR
CONCENTRATION BELOW TLV .
Protective Gloves:RUBBER OR NEOPRENE.
Eye Protection:CHEM WORK GOGG .PLASTIC FACESHLD.
Other Protective Equipment:WEAR FULL COVER RUBBER CLOTHING.SAFETY HAT.
Work Hygienic Practices:N/K
Supplemental Safety and Health
LD50-LC50 MIX:LC50 RAT INHAL 48 PPM/4 HR,GUINEA PIG INHAL 53 PPM/4
HR.EFFTS OF OVEREXPOS:ANEMIA,HEPATITIS & SHOCK.

Boiling Pt:B.P. Text:107.9C,225F
Melt/Freeze Pt:M.P/F.P Text:1.17C,34F)
Decomp Temp:Decomp Text:N/K
Vapor Pres:40 MMHG
Vapor Density:5.3,AIR=1
Spec Gravity:1.675 (WATER=1)
Evaporation Rate & Reference:1 (BUTYL ACETATE=1)
Solubility in Water:DECOMPOSES
Appearance and Odor:AT ROOM TEMPERATURE:OILY LIQUID COLORLESS TO YELLOW
WITH PUNGENT ODOR.
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
H*2O,ALKALIS,ORGANICS.VIOLENT RXN W/ ACETIC ACID,AL,DIMETHYL
SULFOXIDE,POTASSIUM,SODIUM,H*2O,NO*3 & ORGANIC MATTER.
Stability Condition to Avoid:DO NOT USE WATER-VIOLENT REACTION.
Hazardous Decomposition Products:PHOSPHORUS ACIDS & HYDROCHLORIC
ACID.POCL*3 IS A VERY REACTIVE CHEMICAL.
Conditions to Avoid Polymerization:WILL NOT OCCUR.

Product ID:PHOSPHORUS OXYCHLORIDE
MSDS Date:08/19/1986
FSC:6850
NIIN:00N010186
MSDS Number: BHNQR

Waste Disposal Methods:DISPOSAL MUST BE IAW FEDERAL,STATE & LOCAL
REGULATIONS .ACCEPTABLE TO COVER WITH DIRT & REMOVE ALL CONTAM MATL
TO SECURE CHEMICAL LANDFILL.CONTACT APPROPRIATE REGULATORY AGENCIES
PRIOR TO DISPOS AL.

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